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Arnault
HEYNDERICKX
Associate Professor
CINaM, UPR
3118. - GCMO2
Groupe de
Chimie Organique Moléculaire et Modélisation
Facultes de
Sciences de Luminy.
Case 901,
bât TPR1 entrée E, 6 étage
13288 Marseille Cedex 9.
Phone: (33) 4 91 82 93 41
Fax: (33) 4 91 82 93 01
E-mail: heynderi@luminy.univ-mrs.fr
Webpage: http://heynderickx.webdynamit.net
Personal Information:
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Date of Birth: February
11, 1970
Place of Birth: Rueil malmaison (
Citizenship: Français
Family status: soon
divorced.
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Education
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|
1997 |
Ph.D
in Organic Chemistry, Thesis: Synthèse et fonctionnalisation par métallation de fluoro et trifluorométhyldiazines Research
advisors: Prof. Nelly Plé, Prof. Alain Turk and Prof. Guy
Quéguiner |
|
1986 |
B.Sc.
in Chemistry, |
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Professional experience
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|
1998 - Present |
Associate Professor GCOM2 - University of Aix-Marseille
II Current director: Prof. André Samat |
|
1997-1998 |
Postdoctoral researcher ATER in
the Laboratory of Organic and Bioorganic chemistry - URA CNRS 1320 - Supervisors: Prof. Robert Guglielmetti |
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Research interest
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|
I.
Design, synthesis and performance of photoresponsive molecules,
materials and devices. Fundamental aspects and the present and future
applications and developments in photochromism ü
Supramolecular Assemblies, liquid crystals, polymers, sol-gels,
Microcrystal, thin films… ü
Structure - activity correlation, Optical and electrical properties of
organic functional materials. ü
Biological or biomimetic systems Potential applications: information storage and readout,
optoelectronics |
|
II. Developing fluorophores Probes to
Study Biomembranes |
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Teaching experience:
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|
M1 |
Master Physico-Chimie des Matériaux - UE
1.4 Chimie des Polymères |
|
ESIL |
Organics
Materials |
|
CHI
5 |
Analytical
Chemistry and Spectroscopy |
|
CHI 13 |
Electrochemistry,
Chemical Kinetics |
|
CHI4 |
Structures
and properties of matter |
|
CHI 17 |
An
Introduction to Scientific Research |
|
CHI8 |
Organic
Chemistry |
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Public Professional Activities:
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Ø
Member
of Committee on Hygiene and Security on University of Aix-Marseille II.
Ø
Member
of the organizing committee of Rcom 2 (2ème Rencontre de
Chimie Organique Marseillaise.
Ø
Member
of Committees of the Luminy Faculty
Ø
NMR
Facility Manager for the chemistry department of Luminy Faculty.
Ø
Member
of Committees of French Photochemistry Group (GFP).
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Publications:
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Ple, N.;
Turck, A.; Heynderickx, A.; Queguiner, G.
Journal
of Heterocyclic Chemistry
(1994), 31(6), 1311-15.
Metalation
of diazines. XI. Directed ortho-lithiation of fluoropyrimidines and application
to synthesis of an azacarboline.
Ple, N.;
Turck, A.; Heynderickx, A.; Queguiner, G.
Synthesis
and metalation of trifluoromethylpyrimidines. Metalation of diazines. XVI.
Journal
of Heterocyclic Chemistry
(1997), 34(2), 551-556.
Ple,
Nelly; Turck, Alain; Heynderickx, Arnault; Queguiner, Guy
Tetrahedron (1998), 54(33), 9701-9710.
First
metalation of iodo diazines. Iodo and nitrogen directed metalations. Diazines
XXII.
Ple,
Nelly; Turck, Alain; Heynderickx, Arnault; Queguiner, Guy.
Tetrahedron (1998), 54(19), 4899-4912
Functionalization
by metalation of fluoropyrazine. Diazines XXI.
Lokshin,
Vladimir; Heynderickx, Arnault; Samat, Andre; Pepe, Gerard; Guglielmetti,
Robert.
Tetrahedron
Letters (1999), 40(37), 6761-6764.
New
and facile synthesis of 3-styrylflavones.
Heynderickx,
A.; Lokshin, V.; Samat, A.; Guglielmetti, R.; Pepe, G.
Zeitschrift
fuer Kristallographie - New Crystal Structures (2000), 215(4), 553-554.
Heynderickx,
Arnault; Samat, Andre; Guglielmetti, Robert.
Journal
of Heterocyclic Chemistry
(2001), 38(3), 737-742.
Synthesis
of new benzylpyridines as potential photochromic compounds.
Heynderickx,
Arnault; Samat, Andre; Guglielmetti, Robert.
Synthesis (2002), (2), 213-216.
A
one-pot synthesis of hindered 2,3-diarylbenzo[b]thiophenes via Suzuki reaction.
Heynderickx,
Arnault; Samat, Andre; Guglielmetti, Robert
Synthesis (2002), (12), 1747-1751.
Synthesis
of 2-benzyl-1,10-phenanthrolines substituted by sulfoxide or sulfone groups as
potential photochromic compounds.
Toudic,
Frederic; Heynderickx, Arnault; Ple, Nelly; Turck, Alain; Queguiner, Guy
Tetrahedron
2003, 59(33), 6375-6384
Regioselective
synthesis and metalation of (tributylstannyl)fluoropyrazines. Application to
the synthesis of some new fluorinated diazine liquid crystals.
A.
Heynderickx, R. Guglielmetti, R. Dubest, J. Aubard, A. Samat
Synthesis, 2003, 1112-1116.
Sulfinyl-
and Sulfonyl-Substituted 2-Benzoxazoles and 2-Benzylbenzothiazoles as Potential
Photochromic Compounds.
A. Heynderickx,
A.M. Kaou, C. Moustrou, A. Samat, R. Guglielmetti.
New J.
Chem. 2003, 27,
1425-1432.
Synthesis
and Photochromic behaviour of new dipyrrolyperfluvrocyclopentenes.
Khedhiri,
M. Rzaigui, A. Corval, R. Casalegno, A. Heynderickx
Z.
Kristallog NCS 2004,
219(1), 21-22.
A-E. Navarro, F. Moggia, C. Moustrou,
A. Heynderickx, F. Fages, P. Leriche, H. Brisset
Tetrahedron 2005, 61, 423-428.
Synthesis,
Electrochemical and Photochromic behaviour of a series
of(1,4-dithiafulven-6yl)substituted 3H-Naphtho[2,1-b]pyran derivatives.
A. Samat,
V. Lokshin, A. Heynderickx, V. Khodorkovsky.
Mol.
Cryst. Liq. Cryst.,
2005, 430, 23-30
Revisting
Old Series And Rational Design Of Novel Photochromism.
N. Impagnatiello, A. Heynderickx, C. Moustrou, A. Samat.
Mol. Cryst. Liq. Cryst., 2005, 430, 243-248.
Synthesis
And Photochromic Properties Of Functional Diarylethenes With A
[1,3]Dithiol-2-One(Thione) Bridging Unit.
P.
Smimmo, F. Ortica, U. Mazzucato, G. Favaro, A. Heynderickx, C. Moustrou, A.
Samat.
Mol.
Cryst. Liq. Cryst. 2005,
430, 267-272.
Photophysics
and Photochemistry of some Dipyrrolylperfluorocyclopentenes.
F.
Ortica, P. Smimmo, U. Mazzucato, G. Favaro, A. Heynderickx, C. Moustrou, A. Samat.
Photochem.
Photobiol. 2006, 82, 1326-1333.
Photoinduced
processes in dipyrrolylperfluorocyclopentenes.
Ortica,
F.; Smimmo, P.; Zuccaccia, C.; Mazzucato, U.; Favaro, G.; Impagnatiello, N.;
Heynderickx, A.; Moustrou, C.
Journal
of Photochemistry and Photobiology, A: Chemistry (2007), 188(1), 90-97.
Photobehavior
of diarylethenes with thiophenes as aryl groups and dithiole-2-thione and
dithiole-2-one at the ethenic bond.
A. El Yahyaoui, G. Félix, A. Heynderickx*, C. Moustrou, A. Samat.
Tetrahedron 2007,
63(38), 9482-9487
Convenient
Synthesis of Photochromic Symmetrical or Unsymmetrical
Bis(heteroaryl)maleimides via The Suzuki-Miyaura cross-coupling Reaction.
L.
Bougdid, A. Heynderickx,
Tetrahedron
2007, 63(34), 8242-8249..
First
Synthesis of Nitro-Substituted 2,2-Diphenyl-2H-1-Benzopyrans via the
Ipso-Nitration Reaction.
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Talks and Posters:
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1- Design and
synthesis of a TTF-bridged bichromophoric system : toward an electromodulation
of photochromic properties
F. Moggia, A-E. Navarro, H. Brisset, A.
Heynderickx, C. Moustrou, A. Samat, F. Fages
7th
European Conference on Molecular Electronics,
2- Synthesis and photochromic properties of functional diarylethene with
a[1,3]dithiole-2(thi)one bridging unit.
C. Moustrou, A. Heynderickx, N.
Impagnatiello And A. Samat.
4th International Symposium On
Photochromism (ISOP’04), Arcachon, 12-15 septembre 2004.
3- Photophysics and photochemistry of some
dipyrrolylperfluorocyclopentenes.
P. Smimmo, F. Ortica, U. Mazzucato, G.
Favaro, A. Heynderickx, C. Moustrou, A. Samat.
4th International Symposium On
Photochromism (ISOP’04), Arcachon, 12-15 septembre 2004.
4- Synthèse de
nouveaux 2H-1-benzopyranes substitués par un motif mono ou
bithiophène, vers l’élaboration de matériaux
à transmission optique variable
L. Bougdid, A. Heynderickx, C. Moustrou Et A. Samat
GIFC 2004 (Giornate Italo Francesi di Chimica),
Genova, 1-2 Avril 2004
5-. Synthèse de
nouveaux 2H-1-benzopyranes substitués par un motif mono ou
bithiophène, vers l’élaboration de matériaux
à transmission optique variable
C. Moustrou, A. Heynderickx, N.
Impagnatiello, A. El Yahyaoui, A. Samat
GIFC 2004 (Giornate Italo Francesi di Chimica),
Genova, 1-2 Avril 2004
6- Elaboration de nouveaux
diaryléthènes. Mémoires optiques
C. Moustrou, A. Heynderickx, N.
Impagnatiello, A. El Yahyaoui, A. Samat
GIFC 2004 (Giornate Italo Francesi di Chimica),
Genova, 1-2 Avril 2004
7- Thermally reversible and bistable
photochromic diarylethenes
P. Smimmo, F.
Ortica, U. Mazzucato, G. Favaro, A. Heynderickx, C. Moustrou, A. Samat.
34mo Congresso
Nazionale of the Physical Chemistry Division of the Italian Chemical Society,
8- Thermal reversibility and bistability in
photochromic diarylethenes
P. Smimmo, F.
Ortica, U. Mazzucato, G. Favaro, A. Heynderickx, C. Moustrou, A. Samat.
Solar 06 Conference, Le Caire, 23-27 janvier 2006, Egypte
9- Study on photochromism of diarylethenes with
a 1-benzyl-5-difluoromethylpyrrole-2-one bridging unit.
A. El Yahyaoui, A. Heynderickx, C. Moustrou, A.
Samat.
GIFC 2006 (Giornate Italo Francesi di Chimica), Turin, les 22-24 Mars
2006, Italie.
10- Successful application of the ipsonitration
reaction to synthesis of a new series of thermoreversible [2H]-benzopyrans.
L. Bougdid, A.
Heynderickx, A. Samat, S. Delbaere, C. Moustrou.
GIFC 2006 (Giornate Italo Francesi di Chimica), Turin, les 22-24 Mars
2006, Italie.
11- Systèmes bistables à base de diaryléthènes
– mémoires optiques.
C. Moustrou, A. Heynderickx, N. Impagniatello Et Andre Samat.
Réunion commune des GDR 2429 (COMES) et 2466 (POM 3), 8-11 Octobre 2003, Collonges-la-Rouge
12-.
Synthèse et caractérisation d'un vinylogue du
tétrathiafulvalène fonctionnalisé par des motifs
naphtopyranes : vers une électromodulation des propriétés
photochromiques.
F. Moggia, A.-E. Navarro, A. Heynderickx, H.
Brisset, C. Moustrou, F. Fages
SAJEC 2003, Gujan Mestras, France, 13 au 15
octobre 2003.
13 - Elaboration de nouveaux
2H-1-benzopyranes substitués par un motif mono ou bithiophène.
Matériaux à transmission optique variable.
L. Bougdid, A. Heynderickx, C. Moustrou, A. Samat.
3ème Rencontre de Chimie Organique de Marseille (RCOM3), 6-7 Mai 2004
14- Elaboration de nouveaux
diaryléthènes bistables
A. El Yahyaoui, A. Heynderickx, C. Moustrou, A. Samat.
GDR 2466 (POM 3), réunion plénière, les 19-20 Mai
2005, Marseille-Luminy.
15 - La réaction d’ipsonitration appliquée à
la préparation de nouveaux [2H]-benzopyranes thermoréversibles.
L. Bougdid, A. Heynderickx, S.
Delbaere, A. Samat, C. Moustrou.
GDR 2466 (POM 3), réunion plénière, les 19-20 Mai
2005, Marseille-Luminy